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Mechanistic implications of the stereochemistry of singlet oxygen-olefin reactions

Lawrence B. Harding, William A. Goddard III

1978Tetrahedron Letters, 19(8), 747-75027cited

Abstract

We analyze the stereoselectivity of singlet oxygen-olefin reactions, concluding that a biradical peroxyl intermediate is involved and that experimental results are inconsistent with perepoxide intermediates.

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Harding, L. B. & III, W. A. G. (1978). Mechanistic implications of the stereochemistry of singlet oxygen-olefin reactions. *Tetrahedron Letters*, *19*(8), 747-750. https://doi.org/10.1016/s0040-4039(01)85384-3