Electronic states of chromium carbene ions characterized by high-resolution translational energy loss spectroscopy
M. A. Hanratty, Emily A. Carter, J. L. Beauchamp, William A. Goddard III, A. J. Illies, M. T. Bowers
1986Chem. Phys. Lett., 123(4), 239-2425cited
Abstract
The electronic states of the unsaturated organometallic carbene CrCH_2^+ are investigated using high-resolution translational energy loss spectroscopy. The observed energy loss feature (1.05 ±0.2 eV) is in good agreement with theoretical calculations which predict two higher lying states, ^6B_1, and ^6A_1 at 0.78 and 0.82 eV respectively, above the ^4B_1 ground state of CrCH_2^+.
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Cite this publication
Hanratty, M. A., Carter, E. A., Beauchamp, J. L., III, W. A. G., Illies, A. J., & Bowers, M. T. (1986). Electronic states of chromium carbene ions characterized by high-resolution translational energy loss spectroscopy. *Chem. Phys. Lett.*, *123*(4), 239-242. https://doi.org/10.1016/0009-2614(86)80064-1