Singlet-triplet energy gaps in chlorine-substituted methylenes and silylenes
Seung Koo Shin, William A. Goddard III, J. L. Beauchamp
Abstract
The singlet-triplet splittings of chlorine-substituted methylenes and silylenes have been studied by using the ab initio generalized valence bond (GVB) dissociation-consistent configuration interaction (DCCI) method. All chlorine-substituted methylenes and silylenes have singlet ground states, with calculated singlet-triplet splittings of 6.0, 20.5, 35.8, and 55.2 kcal/mo] for CHCl, CCl_2, SiHCl, and SiCl_2, respectively. We expect these results to be within 1 kcal/mo] of experiment. The DCCI result strongly suggests that the correct experimental singlet-triplet splitting of CHCl is 6.4 ± 0.7 kcal/mol. [Photoelectron studies of CHCl^- lead to either 11.4, 8.9, 6.4, 3.9, or 1.4 kcal/mo), depending on assignment.]
Group Members
Shin, S. K., III, W. A. G., & Beauchamp, J. L. (1990). Singlet-triplet energy gaps in chlorine-substituted methylenes and silylenes. *J. Phys. Chem.*, *94*(18), 6963-6969. https://doi.org/10.1021/j100381a010