Facile Functionalization of a Metal Carbon Bond by O-Atom Transfer
Brian L. Conley, Somesh K. Ganesh, Jason M. Gonzales, William J., III Tenn, Kenneth J. H. Young, Jonas Oxgaard, William A. Goddard III, Roy A. Periana
2006J. Am. Chem. Soc., 128(28), 9018-901958cited
Abstract
The facile conversion of M−R to M−OR that could be useful for the functionalization of electron-rich metal alkyl intermediates is shown to proceed via a Baeyer−Villiger-type pathway involving a nonredox, electrophilic, O-atom insertion in reactions with non-peroxo O-donors.
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Conley, B. L., Ganesh, S. K., Gonzales, J. M., Tenn, W. J. I., Young, K. J. H., Oxgaard, J., III, W. A. G., & Periana, R. A. (2006). Facile Functionalization of a Metal Carbon Bond by O-Atom Transfer. *J. Am. Chem. Soc.*, *128*(28), 9018-9019. https://doi.org/10.1021/ja062417w